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TOXIC POLLUTION OF THE AIR WE  BREATHE IN, EVERY MOMENT OF OUR  LIVES

TOXIC POLLUTION OF THE AIR WE BREATHE IN, EVERY MOMENT OF OUR LIVES

Human being is a living entity as a being one, we have to breathe to exist and the very air that forms the main source of where we draw oxygen molecules for our tissue and cells to utilize is full of adverse and dangerous contaminants commonly referred to as toxic air pollutants or air toxics.

Toxic Air Pollutants
Toxic air pollutants are also referred to as hazardous air pollutants (HAPS) or air toxics and are poisonous substances in the air that come from natural sources (eg. Radon gas released from the ground) or from man made sources (eg. emission of exhaust gases from motor vehicles).  They are generally known to cause harm to the environment or your health.  Inhaling (breathing) toxic air pollutants can increase your chances of experiencing health problems.  Toxic air pollutants may exist as vapors (gases) or particulate matter.  Toxic air pollutants may include metals, other particles, gases absorbed on to particles, and certain vapors from fuels and other sources.  There is a legal difference between air toxics or "Hazardous Air Pollutants" and "Criteria Air Pollutants".  The American National Ambient Air Quality Standards (NAAQS) classified "Criteria Air Pollutants" can cause adverse health and environmental effects, they are not included in the Clean Air Act Title III "Hazardous Air Pollutant" program.   The Clean Air Act (Section 112) at the moment, register a .limited number of toxic air pollutants to be used by (EPA) to identify the initial list of source categories for which, technology-based, toxic air emission reduction standards would be considered. These substances are certain volatile organic chemicals, pesticides, radionuclides and herbicides that are health hazardous, back up by scientific studies of exposure to mammals including humans.  Once released, toxic pollutants can be carried by the wind, away from the original sites, to other locations. Factors such as the terrace of the grounds eg. valleys and mountains plus the physical and chemical structures of the pollutants will result in the eventual distance of distribution and concentration of it. The physical and chemical composition will determine its state of suspension in the air as well as deterioration of it.  Some pollutants are of particular danger because they deteriorate very slowly or not at all such as the case of lead or mercury. These dangerous air toxics can persist in the environment for a long time or forever and can be transported to a long distances.
 

Particulate Matter
Particulate matter – PM or particulates meant the many varieties and sizes of suspended particles in the air and include combustion products such as ashes or soot, tiny droplets of liquids known as aerosols, and wind carried dust. The size of particulates can be from visible grains of sand and dust to tiny particles so small that you can only see them with a microscope.
Particulates can impair visibility and poses a serious health threat to human beings. Our respiratory systems can only filter out larger particles but cannot do so with particles less than 10 microns in diameter and damaging to the lungs. Smaller particles ie. 2.5 microns can penetrate very deep into the lungs and do the most harm. Toxic and cancer-inducing compounds can “ride” on these particulates and be directly absorbed into the lungs. These particulates, when “trapped” in the alveoli ( tiny air-sacs) may interfere with oxygen and carbon dioxide interchange. Babies and small children are most susceptible to particulates because of smaller lungs and less mature immune system. The prime sources of PM are agriculture dusts, all types of motor vehicles, wood stores, fire places, industrial emissions, any type of burning, etc.etc. Particulates concentrates in areas of industrial or agricultural activities, in areas of dense population, etc.etc. All these are caused by human intervention, however some particulates are there naturally such as pollen from plants, wind-blown sand and dust, bits of earth from volcanoes and soot from forest fires.

Gases
Gases are chemicals suspended in the air and many of them are invisible. Some gases are useful such as oxygen and some of them are harmful such as sulphur dioxide, nitrogen oxides, carbon dioxide, ozone and volatile organic compounds (VOCs) etc.etc. Gases are created by nature such as oxygen from plants during photosynthesis and others from eruption of volcanoes, lighting and decomposition of plants. Humans also put many types of gases into the air through gas stove burning, in industrial activities etc.etc.

DANGER IN THE AIR AND ATMOSPHERE – INDOOR AT HOME

A growing body of scientific research data has shown that the air within homes and offices can be more seriously polluted than the outdoor air in even the biggest and most industrial cities. Most people spend about 90% of their time indoors at home or office, thus the risks to their health is greater due to indoor pollution as compared to outdoor air pollution. At the same time, those people who may be exposed to indoor air pollutants for the longest time are most often, susceptible to the effects of indoor pollution and these include the very young ( babies and small children), the pregnant, the elderly and the chronically ill, especially those who have respiratory problems e.g. asthma and cardiovascular diseases.  Indoor pollution sources that release gases or particulates – into the air the major cause of bad indoor air quality especially in the homes.  Inadequate ventilation can increase indoor pollutant levels because of not enough outdoor air diluting the emissions from indoor sources and also not transporting indoor air pollutants out of the home. High humidity and temperature can contribute to certain pollutants concentration in the home.  There will be air exchange between the indoor and the outdoor and outdoor air enters and leaves a house by infiltration, natural ventilation and mechanical ventilation.  In infiltration, outdoor air moves into the house through joints, openings and cracks in walls, floors, closed doors and closed windows etc. Air moves through opened windows and doors in natural ventilation. Then, mechanical ventilation are caused by mechanical ventilation devices such as exhaust fans that remove air from rooms such as toilets, kitchens etc. and air conditioning that removes indoor air from the bedroom and dispel it outdoor and take in outdoor air, filter it and distribute it back into the bedroom. When the exchange rate is low between the indoor and outdoor air contents, the pollutant levels in indoor may increase.

Pollutants and Pollutants Sources
Radon (Rn)
Radon is a colourless, odorless and tasteless gas that occurs everywhere. All homes have a problem of radon infiltration as the most common source of indoor radon is the decomposition of uranium in the soil or rock on which the homes are built. Building materials also give off radon in homes. The foremost health effect due to exposure of high concentration of radon is lung cancer, even swallowing water with high radon levels may be dangerous too. The risk of lung cancer is specially high when you smoke in home with high radon level.
Environmental Tobacco Smoke (ETS)
It is define as the mixture of smoke that comes from the burning end of a cigarette, a pipe or cigar, and smoke exhaled by the smoker. It is a complicated mix of over 4,000 compounds of which more than 40 of them are causing cancer in humans or animals. ETS  is also known as “secondhand smoke” and exposure to ETS is also known as “passive smoking” In 1992, EPA completed a major assessment of the respiratory health risks of ETS and reported that ETS is responsible for approximately 3,000 lung cancer deaths each year in nonsmoking adults and damages the respiratory organs of hundreds of thousands of students.  The ETS also increased infants and young children’s risk of lower respiratory tract infections ( pneumonia and bronchitis). They show symptoms of respiratory irritation like cough, excess phlegm and wheeze.  Some children may also have a build-up of fluid in the middle ear, which leads to ear infections, and some children have slightly reduced lung function. People especially children who have asthma when exposed to ETS have had increased severity of symptoms and may even induce non-asthmatic children to develop the disease. Exposure to ETS causes eye, nose and throat irritation and may also affect the cardiovascular system and induce the onset of chest pain.
Biological Contaminants
Indoor air is also been affected by biological contaminants and they include bacterial, viruses, mildew, molds, animal dander, cat saliva, cockcroaches, pollen and house dustmites. Even the protein in urine from rats and mice is a potent allergen. When it dries, it can become airborne. Contaminated central air distribution systems can also act as breeding grounds for mildew and molds and other sources of biological contaminants. A damp and warm environment will encourage the growth of house dust mites, the source of one of the most potent biological allergens. Some biological contaminants trigger allergic reactions, including pneumonitis, allergic rhinitis, and some types of asthma. Influenza, chicken pox and measles are infectious disease which are transmitted through the air. Molds and mildews release disease-causing toxins. Symptoms of health problems induced by biological pollutants are watery eyes, sneezing, shortness of breath, coughing, dizziness, fever, lethargy and digestive problem. Some diseases such as humidifier fever are due to exposure to toxins from micro organisms that grow in large building ventilation system as well as in home heating and cooling systems including humidifiers.

Stoves, Heaters, Fire Places and Chimneys
Unvented kerosene, wood stoves, gas space heaters, fire places and gas stoves are sources of combustions products and the major pollutants are nitrogen dioxide, carbon dioxide and particles. Unvented kerosene heater also produce acid aerosols. Chimneys and flues that are improperly installed or maintained and cracked furnace heat exchangers also produce combustion gases and particles. Pollutants from fire places and wood stoves with no special outdoor air supply can be “back-drafted” into the living room, from the chimney. Wood smoke which seems so natural and harmless contains over 100 different chemicals or compounds and many of them are extremely poisonous and carcinogenic. The particles in wood smoke are too minute to be filtered out and trapped by the nose and upper respiratory system and they penetrate deep into the lungs like tiny daggers and some are even iron coated from combustion. These particles can remain in the lungs for months, years and even for a lifetime, irritating and damaging the delicate lining, causing scarring and chemical changes leading to permanent damage. Wood smoke may be more destructive and dangerous than Environmental Tobacco Smoke (ETS). Biopsies of rural women exposed regularly to wood smoke showed that their lungs were red and raw, ravaged by fissures, much worse than lungs damaged by regular cigarette smoking. Wood smoke decreases lung function and aggravates asthma, emphysema, pneumonia and bronchitis. It stings the eyes and triggers migraines, headaches and allergies. Long term exposure may lead to chronic bronchitis emphysema, arterioclerosis, and nasal, throat, lung, blood and lymph-system cancers. The free radicals unleashed by wood smoke is 40 times more portent than cigarette smoke in attacking the body’s immune system.
Carbon Monoxide (CO)
It is one of the gases released in burning and is colourless, that interferes with the oxygen intake of the body. At lower concentrations, a range of symptoms like headaches, dizziness, nausea, weakness, confusion, disorientation and fatigue even in healthy people and people with chronic heart disease – they have events of increased chest pain.
Nitrogen Dioxide (NO2)
It is a colourless, odorless gas that irritates the mucous membrane in the eye, nose and throat and causes shortness of breath after high concentrations exposure. Repeated exposure of elevated nitrogen dioxide can lead to the development of lung disease such as emphysema and increase infections of the lungs.
Household Products
Organic Chemicals are widely used as ingredients in household products such as cleaning agents, wax, paints and varnishes all contain organic solvents, similarly many disinfecting, cosmetic, degreasing and hobby products. The range of household products that contain potentially harmful substances that contribute to indoor air pollution is diverse and wide-reaching. Even fuels are made up of organic chemicals. All of these products release organic compounds while during usages and gradually and slowly during storage. EPA’s studies found levels of a number of common organic pollutants to be 2 to 5 times higher inside homes that outside, irrespective that the homes were located in highly industrial or rural areas. At the same time, these people who are using the products containing organic chemicals, expose themselves and other people to very high pollutant levels and even after the activity is completed, the elevated concentrations still persist in the air for a longtime.
The ability of organic chemicals to cause health problems depends on the toxicity of the chemicals to human being and it can be highly toxic or none at all. The other factor depends on the length of time exposed and the concentration of exposure. Many organ compounds are known to cause cancer in human or are suspected to. Methylene chloride is known to cause cancer and is present in paint strippers, adhesive removers and aerosol spray paints. Aerosol spray products including health, beauty, and cleaning products – prolonged or excessive exposure to the pesticides released into the air may cause headaches, nausea, shortness of breath, eye, throat and lung irritation, skin rashes, burns and liver damage especially for sensitive people. Another danger is that aerosol containers may explode if exposed to heat, causing burns and serious injury. Chlorine bleaches can irritate and burn skin and eyes. When mixed with other substances to make a cleaning solution can produce very dangerous gas that can be deadly. Even rug and upholstery cleaners may contain some chemicals when inhaled excessively can cause anemia, liver damage, convulsions and possible coma.
The average home contains some 45 aerosol products alone, which include potentially harmful chemicals such as potassium hydroxide, perchloroethylene methylene chloride, mercury, lead arsenate and paradichlorobenzene and the aerosol particles produced thereof which can carry many of these toxic compounds with them, are small enough to bypass the lung’s defences and render harm.
Formaldehyde
It is a colourless, pungent-smelling gas, can cause burning sensations in the eyes and throat, nausea and difficulty in breathing in some humans exposed at elevated levels ( above 0.1 parts per million ). High concentrations can trigger attacks in people with asthma. Research shows that it can cause cancer in animals and may cause cancer in man. It is widely used in building materials and many household products, thus it is present in substantial concentrations in indoors and outdoors. It is found also in unvented, fuel-burning appliances like gas stoves or kerosene space heaters, permanent press quality clothing and draperies, in glues and adhesive and as a preservative in some paint and coating products. Pressed wood products use adhesive that contain urea-formaldehyde (UF) resins include particle board ( used as sub-flooring, shelving, cabinetry and furniture) hardwood paneling ( used for decorative wall covering, in cabinets and furniture) and medium density fibre-board ( used for drawer fronts, cabinet, and furniture tops). Other pressed wood products, such as softwood plywood and flake or oriented strand board also contains phenol formaldehyde (PF) resin.
A number of prefabricated and mobile homes have elevated levels of formaldehyde due to the large amount of high-emitting pressed wood products used in their construction. When the wood products are new, high indoor temperatures or humidity can accelerate release of formaldehyde from these products.
Pesticides
Seventy-five percent of US households used at least one pesticide product indoors last year. Products most often used are disinfectants and insecticides. Research also shows that 80% of most of the pesticides exposure to people occurs indoors and different types of pesticides are found in the air inside homes and in quantity greater or more varied than those in recent use. The possible sources could be contaminated soil or dust that floats on is brought in by walking from outside, stored pesticides containers and household surfaces that collect and release them into the air in the home.
We use pesticides in and around the home such as termiticides against termites, insecticides against insect, fungicides against fungi, rodenticides against rodents and disinfectants against microbes. All these items are sold as crystals, balls, powders, stickers. sprays, liquids and foggers. These pesticides are meant to “kill” the specific types of pests but sometimes “kill” or “half kill”. In addition to the active ingredient, “inerts” ingredients are used to carry the active agent to the targeted pest and some of them can cause health problems. Since both active and inert ingredients can be organic compounds, they also add to the level of airborne organisms in the house. As with other pollutants, the deterioration of the health of the user depends on the duration of exposure and concentration of the pollutants. Eye and lungs are affected resulting in headaches, dizziness , visual disorders and memory impairment for some people after exposure to some organic. In the long term, more serious complication may arise such as cancer. People expose to high levels of cyclodiene pesticides reported to have headaches, dizziness, weakness, tingling sensations, twitching of muscles and nausea and in the long run, might even cause permanent damage to the liver and the central  nervous system as well as causing cancer.
Asbestos
It is a mineral fibre used in construction projects as insulating materials and as a fire-retardant. When asbestos materials are disturbed by sanding, cutting and other fabricating activities, the asbestos fibres are released into the air in homes elevating dangerous concentrations of air borne asbestos and endangering people living in those homes. Those asbestos fibres too small to be seen  eg. 2.5 micron reaches deep into the aveoli of the lungs when they are inhaled in and remain and accumulate there. They can cause cancer, mesothelioma ( a cancer of the chest and abdominal linings) and asbestos ( irreversible lung scarring). All the symptoms only show up after initial exposure many years later.
Lead
It has been recognized as the number one environmental threat to children’s health in USA and definitely a very harmful environmental pollutant. There are too many ways man can be exposed to lead, through air, drinking water, food, contaminated soil, deteriorating paint and dust. Formerly it was used in paint, gasoline, water pipes and many other products. Air borne lead enters the body through inhalation of microscopic particulate containing lead or swallow lead particles or dust. High concentration of airborne lead particles in the house can be lead dust from outdoor sources, including contaminated soil tracked from outside and the use of lead in certain indoor activities such as stained glass making and soldering. Lead affects all your body system at all levels. At low level, it can affect the kidney, blood cells, the brain and central nervous system and at high level, convulsion, coma and even death occurs. The toxic effect on fetuses, babies and young children are even more damaging because of their age, their growing bodies are more sensitive and vulnerable to lead exposure. Those who have been exposed suffers delay in physical and mental development, lower IQ levels, increased behavioral problems and shortened attention span. Children, definitely have higher exposures because they are more likely to get lead dust on their hands and put their fingers or lead-painted or contaminated objects in their mouth.

DANGER IN THE AIR AND ATMOSPHERE - INDOOR AT OFFICE

In many office buildings, the pollutant levels are high due to inadequate ventilation, and many indoor air pollution sources. The most important factor determining the indoor air quality is the presence of pollutant sources. The commonly found office pollutants and their sources are environmental tobacco smoke, formaldehyde from pressed wood products, asbestos from insulating and fire-retardant building materials, cleaning materials and activities, paints, adhesive, rest room air freshners, copying machines, biological contaminants from dirty ventilation systems or moist walls, ceilings, carpets, as well as pesticides, aerosols and disinfectants used by the cleaning and disinfecting lady. Mechanical ventilation systems which are poorly designed operated or maintained can contribute to indoor air problems by not drawing inadequate outdoor air for circulation or wrong location of outdoor air intake vents, bringing in contaminated air saturated with pollutants of motor vehicle exhausts etc. Then again the ventilation system is itself an indoor pollution source by distributing biological contaminants that have multiplied in cooling towers, humidifiers, air conditioners or the interior of ventilation duct. Even if certain portions of the building has been used for specialized purposes such as restaurants, print shop or dry cleaning in the same building can contribute to indoor air pollutants. Underground parking can contribute to carbon monoxide and other components of automobile  exhaust can contaminate the building’s indoor quality through stain walls and elevator shafts.
It has been well established that illnesses such as asthma, hypersensitivity pneumonitis, Legionnaine’s disease and humidifier fever are directly linked to specific building problems. In certain buildings, the occupants may experience symptoms that do not fit the pattern of any particular illness and are difficult to trace to any specific source.  This phenomenon has been called sick building syndrome.  Some people have complaints of dry or burning mucous membranes in the nose, throat and eyes.  They may also have runny or stuffy nose, always seem to be tired or fatigue, have headache, dizziness, nausea, irritability and forgetfulness.

DANGER IN THE AIR AND ATMOSPHERE - ON THE ROAD AND OPEN SPACES

Toxic pollutants in the open comes from many and varied sources and it affects us when we are walking, jogging, sitting, shopping or relaxing in the parks. In addition to those toxic pollutants that exist in indoor air, there are other types and sources of emissions of toxic pollution contributing to toxic gases and particulate as follows :-

a)  On road engine emission (mobile) sources                d)  Agriculture emission sources
b)  Non-road engine emission sources                           e)  Nature aided emission sources
c)  Industrial emission sources                                        f)  Miscellaneous emission sources

On Road Engine emission (Mobile) Sources
Motor vehicles – car, truck and bus, form the main source of air toxics and according to EPA account for as much as half of all cancers attributed to outdoor sources of air toxics. Below is the annual emissions and full consumption for an average light truck.
 
Pollution problem Amount Miles Pollution or Fuel Consumption
Hydrocarbons Urban ozone (smog) and air toxics. 
 
3.8 gm / mile 14,000 114 lbs of H C
Carbon Monoxide 
 
29.5gm / mile 14,000 895 lbs of CO
Nitrogen Oxides Urban Ozone (smog) and Acid Rain 
 
1.85 gm / mile 14,000 58.5 lbs of Nox
Carbon Dioxide 
 
1.2 pound / mile 14,000 16,800 lbs of Co2
Gasoline 
 
0.066 gallon / mile 14,000 915 gallons gasoline
The above are emission figures which contribute to outdoor air pollution. Several of the pollutants from this source are known or probable human carcinogens e.g. benzene is a known human carcinogen while formladehyde, acetaldehyde, 1.3- butadiene and diesel particulate matter are probable human carcinogens.

Some toxic compounds are present in gasoline and are released into the air during evaporation or the leftovers of unburned fuel eg. benzene, toluene and xylene. Formaldehyde, acetaldehyde, disease particulate matter and 1.3- butadiene are not present in fuel but are by products of incomplete combustion. Ozone is not emitted directly but is created in the air through a complex set of chemical reactions involving hydrocarbons, oxides of nitrogen ( emitted by motor vehicles) and sunlight.  It is a highly reactive gas and a major component of smog.  It can damage cells, prolonged or repeated exposures could be a risk factor for cancer.  It irritates the sensitive tissue of the eyes, nose and lungs, causing inflammation, chest pain and difficulty in breathing.  Physically, children are more vulnerable to air pollution than adults because their respiratory defenses are not fully formed.  Carbon monoxide (CO) is a product of incomplete combustion and is especially lethal to heart diseased persons.

Nonroad Emission Sources
Nonroad is a term that comprises a wide collection of engines, vehicles and equipment and include power equipment, recreational vehicles, aviation aircraft, boats, locomotives, farm and construction equipment, generators, lawn and garden  equipment. The majority of nonroad equipment are powered by gasoline engines that burn gasoline or diesel fuel. Pollution from these engines are by-products of the combustion process called exhaust and from evaporation of the gasoline fuel.
Pollutants from nonroad engines include particulate matter from the smoke and odor associated with diesel exhaust, nitrogen oxides, carbon dioxide and carbon monoxide and together they contribute to the overall toxic pollution in outdoor air.

Industrial Emission Sources
The industrial sector encompasses many types of industries that range from those involving transportation, manufacturing, electricity producing, cleaning to assembling. All these industries, however require chemicals and solvent for cleaning, servicing and maintenance of its machinery.  Different types of lubricants and oil will be used to maintain the machines in prime working condition. Waste and different types of pollutants will definitely occur, resulting from the above usages.  During manufacturing , certain parts of the items of manufacturing will be discarded and different types of pollutants will be created – some airborne and some not. At the end of the day, product and service will be produced but toxic pollutants are also mandatory and cover the following industries.
1) Air Transportation Industry
2) Dry Cleaning Industry
3) Electronics and Computer Industry
4) Fossil Fuel Electric Power Generation Industry
5) Ground Transportation Industry
6) Inorganic Chemical Industry
7) Iron and Steel Industry
8) Lumber and Wood Products Industry
9) Metal Casting Industry
10) Metal Fabrication Industry
11) Metal Mining Industry
12) Motor Vehicle Assembly Industry
13) Non-ferrous Metals Industry
14) Non-fuel, Non-metal Mining Industry
15) Organic Chemical Industry
16) Petroleum Refining Industry
17) Pharmaceutical Industry
18) Plastic Resins and Man-made Fibres Industry
19) Printing Industry
20) Pulp and Paper Industry
21) Rubber and Plastic Industry
22) Shipbuilding and Repair Industry
23) Stone, Glass and Concrete Industry
24) Textiles Industry
25) Transportation Equipment Cleaning Industry
26) Water Transportation Industry

Agriculture Emission Sources
Agriculture emission sources are basically from two sources, one is that from agricultural crop production and the second, is from agricultural stock production.
Agricultural Crop Production
Agricultural crop production involves  i) preparing the land for planting of seeds   ii) during growth period   iii) harvesting the mature crops.
i) Preparing the land for planting of seeds involve plowing huge tract of land e.g. for maize or corn and after plowing, the top soil (fine particles) without the protection of vegetation cover can be carried by wind and any pesticides or fertilizers, to many parts of the area, contributing to particulate matters in the air.
ii) During growth period, fertilizers are added to the earth in liquid or dry powder form.  The fine mists of fertilizers will be carried by the wind and so is dry powder form to many areas beyond the area of intent.  This also applies to pesticides in liquid or dry powder form – most often by mechanical apparatus or huge tractor or even by aerial spraying which increases the area of contamination.
iii) Harvesting time will also be another source of polluting the air when machinery are being used, they stirred up the pesticides and fertilizers which are present in the field and send them airborne in the process.  Many countries burn the residue of harvesting e.g. sugar cane fields in Cuba or rice fields in Indonesia or in slash and burn traditional planting method by the jungle people of Borneo.
Many types of pesticides are used in the control and eradication of pests and these pesticides pose an equally dangerous situation to human beings and some are especially dangerous and have been referred as Persistent Organic Pollutants (POPs) because they are readily absorbed in fatty tissue, their concentrations in the body can be magnified up to 70,000 times the background levels. Some of the POPs used in agriculture are:
Aldrin
Used to control grasshoppers, termites and other insect pests, it can also kill birds, fishes and even humans.  Many shorebirds and waterfowl along the Texas Gulf Coast in the United States were killed after consumption of Aldrin - treated rice or dead animals which had consumed the rice.
DDT
It is used to eradicate malaria-bearing mosquitoes amongst agricultural crops.  It is very stable and half of the application can remain in the soil for the next 10 to 15 years and it is so wide spread that traces have been found in the Artic and Antartic regions.
Chlordane
It is used to kill termites and used as a broad spectrum insecticide on crops.  It is fatal to bob white quail, pink shrimp, mallard ducks and is a possible human carcinogen which affects the immune system.  Contamination is basically in air pollution and can be found even in the indoor air of homes in Japan and the United States.
Deldrin
It is used on textile pests, diseases bearing insects and termites.  Lethal to aquatic animals, especially frogs and fishes.  Traces of this POPs are in the air, water, soil, birds, fishes, snakes, mammals and even human beings.  It is even found in pasteurised milk in a US survey.
Endrin
It is used to control rodents in the crops, such as cotton and grains.  It is highly toxic to fish and may remain active in the soil up to 12 years after application.
Mirex
It is used to eradicate fire ants and is toxic to several types of plants, crustaceans and fish.  It remains lethal for up to 10 years after application.  Humans can be exposed to it through many methods, one of them is during spraying or harvesting time, when the airborne particles are carried by the wind.
Heptachlor
Also used on soil insects, cotton insects and malaria bearing mosquitoes.  It is killing off several types of wild birds.  It is also a possible human carcinogen which have been found in the blood of cattle in Australia and the United States.
Toxaphene
It is used on crops and livestock and can remain toxic up to 12 years from first application.  It is very toxic to fish and a possible human carcinogen.
 

Agricultural Stock Position
Agricultural Stock Production also contributes to air pollution in outdoor air.  One of the most contributory item is animal wastes which includes the fecal and urinary wastes of livestock and poultry.  The pollutants can be transported in many ways from confined or unconfined animal facilities and one of the ways is by wind which picks up dry dust particles carrying the animal waste together with dangerous microbes and transport it to many areas far from the area of pick-up.  Over-grazing of land will reduce vegetation coverage on grazing land which leads to exposed soil.  Dust and fine particulate matters will be picked up by the wind for air distribution of the pollutants.  Even when big herds of cattle run across such areas of exposed soil, they raise up dirt, dust and fine particles carrying toxic contaminants which also will be airborne by such action.

Nature Aided Emission Sources
Nature aided emission sources consist of those not made by man, such as volcanic eruptions, a flower’s pollen carried by the wind, sand storm, forest burning through natural ignition by lighting.  Volcano activities emit large quantities of toxic gases and particulate matters spreading over vast areas and cover upwards, downwards and all around due to the explosive force of its eruptions.  In fact, so much dust, smoke and pollutants, most of which are hazardous in nature, fill the air that large areas around it are covered by haze for long period of time and also caused acid rain to fall in even areas far from the point of explosion. Similarly, forest fires in especially dry areas create such condition in Indonesia in 1998 that covers a large part of South East Asia with haze for many months.  Many people suffered from the ill effects and a number of people were hospitalized or had to seek medical care due to aggravation of their health problems especially, those suffering from asthma and bronchitis.

Miscellaneous Emission Sources
These would cover basically man-made emission sources, such as open burning of rubbish especially tires, outdoor tobacco smoking, festivals fireworks  e.g. Guy Fawkes day, Chinese New Year, burning logs in camp activities which includes chestnut roasting, boy scout camp fires, etc.  All the above activities in burning release a lot of dangerous gases such as carbon monoxide, formaldehyde gas, nitrogen oxide, polycyclic aromatic hydrocarbons and 100 different chemical compounds – many which are extremely poisonous and carcinogenic.  Wood smoke containing particulate too minute to be filtered out and trapped by the nose and upper respiratory system, often ends up deep in the aveoli of the lungs damaging them permanently, and can remain there for life. 

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